蒲河流域降雨侵蚀力时空分布规律研究

降雨侵蚀力时空分布规律是研究土壤侵蚀预报的基础,是反映流域降雨对土壤侵蚀程度的重要指标.根据蒲河流域9个水文气象站的日降雨量资料,分析蒲河流域的降雨侵蚀力时空分布规律.研究可知:蒲河流域在37年的长系列中,年降雨量与年降雨侵蚀力的变化趋势都呈逐步上升趋势,其变化趋势并不明显.全年降雨侵蚀力主要集中在6—9月,年内降雨侵蚀力的高峰值则主要出现在8月,年内降雨侵蚀力的分布呈明显的单峰型.蒲河流域多年平均降雨侵蚀力变化趋势大致由流域的东北部向西南部逐步降低.     

Two-step pyrolytic engineering to form porous nitrogen-rich carbons with a 3D network structure for Zn-air battery oxygen reduction electrocatalysis

It is of great urgency to design inexpensive and high-performance oxygen reduction reaction (ORR) electrocatalysts derived from biowastes as substitutes for Pt-based materials in electrochemical energy-conversion devices. Here we propose a strategy to synthesize three-dimensional (3D) porous nitrogen-doped network carbons to catalyze the ORR from two-step pyrolysis engineering of biowaste scale combined with the use of a ZnCl₂ activator and a FeCl₂ promotor. Electrochemical tests show that the synthesized network carbons have exhibited comparable ORR catalytic activity with a half-wave potential (~0.85 V vs. RHE) and outstanding cyclical stability in comparison to the Pt/C catalyst. Beyond that, a high electron transfer number (~3.8) and a low peroxide yield (<7.6%) can be obtained, indicating a four-electron reaction pathway. The maximum power density is ~68 mW cm^?2, but continuous discharge curves (at a constant potential of ~1.30 V) for 12 h are not obviously declined in Zn-air battery tests using synthesized network carbons as the cathodic catalyst. The formation of 3D porous structures with high BET surface area can effectively expose the surface catalytic sites and promote mass transportation to boost the ORR activity. This work may open a new idea to prepare porous carbon-based catalysts for some important reactions in new energy devices.     

Sn-induced CuO–CeO2 catalysts with improved performance for CO preferential oxidation in H2-rich streams

Sn modified CuO–CeO₂ catalysts with different Sn loadings were prepared by a facile, green and solvent-free method. The effect of Sn/Ce ratio over Sn–Cu–Ce-x (x = 0, 1, 2.5, 5, 7.5) samples on CO activity and O₂ selectivity was investigated. The samples were characterized by various techniques using N₂-adsorption/desorption, XRD, H₂-TPR, XPS, Raman and in-situ DRIFTS. It was revealed that stronger interaction between acitve sites and support, higher amounts of Sn²⁺ and Ce³⁺, associated with increased amount of oxygen vacancies, were observed on the catalyst of Sn–Cu–Ce-5. As a result, the optimized catalyst displayed an excellent catalytic performance even in the presence of CO₂ and H₂O. In this sense, probing the Sn modified CuO–CeO₂ catalyst can elucidate some useful keys for the development of high CO₂ and H₂O-resistance catalyst during CO-preferential oxidation in H₂-rich streams.     

Study of aroma compound formations and transformations during Jinxuan and Qingxin oolong tea processing

We characterised the formation and dynamic changes in the main aroma compounds produced during the manufacturing process of Jinxuan and Qingxin oolong tea. Thirty-five aroma compounds were investigated. Subsequent principal component and cluster analyses showed that the fresh leaves, spread leaves and rocked leaves of the two varieties of tea were distinguished from each other. Particularly, the aldehyde and ‘other’ compounds showed the highest correlation coefficients (0.71 and −0.70) among the principal. The heat map showed that the proportions of acetic acid, 3-methylbutanal and 2-methylbutanal significantly changed during the manufacturing process of the two tea varieties. The key amino acids (isoleucine, leucine, valine and aspartic acid) and enzymes (branched-chain amino acid aminotransferase, aspartate aminotransferase and acetaldehyde dehydrogenase) involved in the synthesis of 3-methylbutanal and 2-methylbutanal differed between the two varieties during manufacture. Our study reveals the characteristics of different varieties of oolong tea and their aroma formation after manufacture using the same process.     

A mixed phase lanthanum vanadate in situ induced by graphene oxide/graphite carbon nitride for efficient photocatalytic hydrogen generation

A mixed phase LaVO₄ with high dispersion was in situ induced and implanted in graphene oxide-graphite carbon nitride composite. The obtained nanocomposite (GO–C₃N₄–LaVO₄) showed high and stable photocatalytic activity for hydrogen evolution, which significantly benefited from the improved charge separation and light absorption in the special composite photocatalyst as evidenced by UV–vis spectra, fluorescence spectrum, photocurrent response and electrochemical impedance. The fabrication strategy of mixed phase LaVO₄ in the GO-C₃N₄ provides a new idea for constructing cheap and active organic-inorganic semiconductor photocatalysts for hydrogen generation.     

薄板坯连铸连轧流程专利分析

以Orbit专利分析平台为主要研究工具，从专利文献中抽取专利数量指标和专利质量指标来构建评价薄板坯连铸连轧技术竞争力和企业创新能力的指标体系，结合其他文献研究的成果，从产业发展的实际出发做出分析，系统揭示了自薄板坯连铸连轧技术开发以来的技术进步、专利布局、发展演化、国内外发展现状、技术竞争实力等，有助于在专利文献提供的线索启发下开发新产品、新技术，从而有效提高研发效率。     

High-Tg porous polyimide films with low dielectric constant derived from spiro-(adamantane-2,9′(2′,7′-diamino)-fluorene)

Porous polyimide (PI) films with low dielectric constants and excellent thermal properties have been a pressing demand for the next generation of high-performance, miniature, and ultrathin microelectronic devices. A series of novel porous PI films containing fluorenyl-adamantane groups were prepared successfully via thermolysis of poly(ethylene glycol) (PEG) added in the PI matrix. The cross-sectional morphologies of porous PI films showed closed pores with diameters ranging from 135 to 158 nm, which were uniform and regular in shape without interconnectivity. These porous PI films exhibited excellent thermal properties with a glass-transition temperature at 376 °C whereas the 5% weight loss temperature in air excess of 405 °C due to enhanced rigidity afforded by fluorenyl-adamantane groups. Accompanied by thermolysis content of PEG increasing from 0 to 20 wt %, the density of porous PI films decreased, and the corresponding porosity grew significantly from 0 to 11.48%. Depending on porosity, the dielectric constant and dielectric loss of porous PI films significantly declined from 2.89 to 2.37 and from 0.050 to 0.021, respectively. These excellent properties benefit the as-prepared porous PI films for application as interlayer dielectrics, integrated circuit chips, or multichip modules in microelectronic fields. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47313.